There are several ways of doing this, and there are a few object layers here, which can be confusing:
Although some things can be done with generic astropy Tables, other VO operations can only be done with VO Tables or VOTableFile objects.
This is easiest to see with an example.
import io, numpy
from astropy import table as aptable
from astropy.io import votable as apvot
myaptable=aptable.Table(
numpy.array([
[19.0186, 46.7304],
[20.2887, 40.4703],
[125.886, 21.3377],
[136.002, 21.9679],
[141.057, 40.6372],
[146.700, 22.0116],
[148.785, 14.2922],
[149.751, 17.8168],
[175.039, 15.3270],
[191.542, 30.7317],
[194.913, 28.8959],
[199.026, 41.5011],
[206.577, 43.8511],
[209.963, 38.1821],
[213.556, 15.6214],
[219.967, 42.7421],
[226.693, 12.8502],
[237.489, 20.8057],
[241.519, 20.8014],
[317.088, 18.2002],
[329.235, 6.64845],
[333.830, 37.3012] ]),
names=["RA","DEC"])
print(type(myaptable))
print(myaptable)
myvotablefile = apvot.from_table(myaptable)
print(type(myvotablefile))
for r in myvotablefile.resources:
mytable=r
for t in r.tables:
print(t)